vinyl

(redirected from vinylic)
Also found in: Dictionary, Thesaurus, Medical, Encyclopedia, Wikipedia.
Related to vinylic: allylic

on vinyl

On a phonograph record. I've always been told music sounds better on vinyl, but I honestly can't hear one bit of difference. More and more musicians are choosing to release their albums on vinyl alongside digital formats.
See also: on, vinyl

vinyl

(ˈvɑɪnlæ)
n. phonograph records. I got some new vinyl. Come over and listen.

on vinyl

In the medium of phonograph recordings: an old song available only on vinyl.
See also: on, vinyl
References in periodicals archive ?
Black crystals, Yield (1.97 g, 90%), m.p 178-180[degrees]C, IR (KBr, [v.sub.max] in [cm.sup.-1]): 3432 (-NH), 3178 (=C-H), 1909 (C=N), 1628 (C=C), 1700 (C=O), [sup.1]H NMR (DMSO-[d.sub.6], 400 MHz) [delta] ppm: 7.09-7.13 (d, 1H, -C=CH- vinulic proton, [J.sub.H-H] = 16.4 Hz), 7.3-79 (m, 8 aryl, 4 phenyl), 8.09-8.13 (d, 1H, -CH=C-, vinylic proton, [J.sub.H-H] = 16.4 Hz), 10.2 (s, 1H, -NH of benzimidazole), [sup.13]C NMR (DMSO-[d.sub.6], 100 MHz) d ppm: 102.29, 106.24, 108.53, 110, 112, 120, 121, 122, 128.51, 129, 130, 132, 142, 148, 152, 190.91 (12 aryl carbons, 6 phenyl carbons, 2 vinylic carbons, 1 imidazole quaternary carbon and 1 carbonyl carbon), MS (m/z): 343.2 ([M.sup.+*]), Anal.
(R)-tert-Butyl-3-(allyloxy)pyrrolidine-1-carboxylate (6, Method C) was isolated as a clear oil (79.2%); [sup.1]H NMR [delta] 5.78 (m, [sup.1]H, vinylic CH); 5.10 (dd, [delta] = 4.0 Hz, 9.8 Hz, 2H, vinylic C[H.sub.2]); 3.94 (m, [sup.1]H, ring diastereotopic O-CH); 3.84 (m, 2H, diastereotopic O-C[H.sub.2]); 3.30 (m, 4H, ring N-C[H.sub.2]); 1.84 (m, 2H, diastereotopic ring 4-C[H.sub.2]); 1.34 (s, 9H, t-BOC C[H.sub.3]); [sup.13]C NMR [delta] 28.7, 30.7, 31.7, 43.7, 44.2, 50.9, 51.6, 70.0, 79.3, 84.6, 117.2, 134.7, and 154.7; IR (film) 3081, 2977, 2933, 2884, 1698, 1478, 1455, 1365, 1254, 1169, 1118, and 1079 [cm.sup.?1]; EIMS (70 eV): 227 [[M].sup.+], 171 [[M-[C.sub.4][H.sub.8]].sup.+], 156 [[M-t-BuO].sup.+], 113 [[[C.sub.5][H.sub.7]N[O.sub.2]].sup.+], and 57 [[t-Bu].sup.+].
[sup.1]H NMR in (DMSO-[d.sub.6]), [delta]: 2.25 (s, 3H, -C[H.sub.3]); 4.91-4.84 (m, 2H, -O-C[H.sub.2]-C[F.sub.3]); 5.60 (s, 2H, -N-CH2-pyridine ring); 7.24-7.19 (d, 1H, vinylic proton); 7.93 (s, 1H, indole ring protons); 7.72 (d, 1H, vinylic proton); 7.35-8.30 (m, 9H, Ar-H); 7.49 (d, 1H, pyridine-H); 8.27 (d, 1H, pyridine-H).
The Type II coagent provided no increase in delta torque for highly unsaturated polymers, perhaps due to the relative ease of allylic hydrogen abstraction from the polymer backbone compared to the vinylic group of the coagent.
Ibis, The Vinylic S, N- Reactions of Nitrodienes with Heteroatom- Substituted Nuchleophilies and their Structural Studies, Heteroatom Chem., 26, 51 (2015).
PBD-DA maintained an extended scorch safety, as the predominant radically active component is vinylic unsaturation.
The characteristic sharp peaks of pure NeemAzal pesticide are at 3471 (O--H stretching), 2924 (aromatic and/ or vinylic C--H), 2856 (aliphatic C--H), 1742 (carbonyl stretching), 1459 [cm.sup.-1] (C[H.sub.2] asymmetric deformation) and 1097 [cm.sup.-1] (C--O groups) [34, 35].
Yield: 60%; 1 H-NMR: (500 MHz DMSO-d 6 ): d H 7.84-6.66 (m 22H Aromatic) 5.18 (m 2H Vinylic) 3.80 (s 6H 2 x OCH 3 ).
These results are in a good agreement with similar TA-doped membranes obtained by grafting various basic vinylic monomer onto fluorinated polymer films [3].
The disappearance of the 5.2, 5.8, and 6.7 ppm peaks (vinylic protons) confirms the polymerization of the monomeric unit.
The first step of the reaction with both is an addition reaction to give different intermediates 9 and 10, 9 is then protonated to give the vinylic thioether 11 whereas the intermediate 10 eliminates the sulfinate anion to 11 (Scheme-2).
In anionic polymerization according to ring-opening mechanism polyethers with vinylic substituents are formed (1).
The [.sup.1]H NMR spectrum of PDTOFV displayed complex multiple peaks in the range [delta] 8.25-6.52 ppm corresponding to the aromatic and vinylic protons.
This fact encouraged us to apply this curing system to DGEBA/esterified Boltom H30 formulations in order to obtain phase-separated thermosets when using vinylic Boltom H30 hyper-branched as modifier.
The signals of aromatic carbons of benzofuran group observed between 154.23 and 112.28 ppm, except of the signals at 127.09 and 117.29 ppm, are due to vinylic ipso carbon next to ester carbonyl and vinylic methylene carbon (=[CH.sub.2]), respectively.